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* a Scottish poet (31 December 1830- 5 January 1867)
* Alexander Smith (chemist) (1865–1922), American chemist and author
* Alexander Smith (bishop) (1694–1767), Roman Catholic bishop
* Alexander Gordon Smith (born 1979), British author of books for children and young adults
* Alexander Hale Smith (1838–1909), religious leader
* Alexander H. Smith (1904–1986), American mycologist
* Alexander Howland Smith, Scottish document forger in the 1880s
* Alexander Kennedy Smith (1824–1881), Scottish/Australian engineer and politician
* Alexander McCall Smith (born 1948), "Sandy", writer and professor of medical law
* Alexander Mortimer Smith (1818–1895), soldier, businessman and political figure
* Alexander O. Smith (born 1973), English/Japanese translator and writer
* Alexander Wilson Smith (1856–1913), farmer and political figure in Ontario, Canada
* Alexander Lockwood Smith (born 1948), New Zealand politician
* a professional American football quarterback for the San Francisco 49ers of the National Football League

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