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We see rainbows because of the geometry of raindrops. When the sun shines from behind us into the rain, incident rays of light enter the drop and are refracted inwards. They are reflected from the back surface of the raindrop, and refracted again as they exit the raindrop and return to our eyes. Refraction is responsible for splitting the sunlight into its component colors.

Read more >http://www.webexhibits.org/causesofcolor/13.html
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