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As to where the materials came from, before there were materials (in other words atoms and molecules), there were subatomic particles. And before there were subatomic particles, there was pure energy. We know we can convert energy into matter and back again - the only requirement being that it is done in accordance with the laws of conservation.
One hypothesis, consistent with all current knowledge, is that the primal energy came from a false vacuum that formed by means of a random quantum fluctuation.
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